High‐Performance LiNi0.5Mn1.5O4 Spinel Controlled by Mn3+ Concentration and Site Disorder

Authors: Jie Xiao, Xilin Chen, Peter V. Sushko, Maria L. Sushko, Libor Kovařík, Jijun Feng, Zhiqun Deng, Jianming Zheng, Gordon L. Graff, Zimin Nie, Daiwon Choi, Jun Liu, Ji‐Guang Zhang, M. Stanley Whittingham - Advanced Materials 2012 cited by 479

The complex correlation between Mn3+ ions and the disordered phase in the lattice structure of high voltage spinel, and its effect on the charge transport properties, are revealed through a combination of experimental study and computer simulations. Superior cycling stability is achieved in LiNi0.45Cr0.05Mn1.5O4 with carefully controlled Mn3+ concentration. At 250th cycle, capacity retention is 99.6% along with excellent rate capabilities. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.