Giant Single‐Molecule Magnets: A Mn84 Torus and Its Supramolecular Nanotubes

著者: Anastasios J. Tasiopoulos, A. Vinslava, Wolfgang Wernsdorfer, Khalil A. Abboud, George Christou - Angewandte Chemie International Edition 2004 被引用: 889

A meeting of two magnetic worlds: The giant (ca. 4.2 nm) {Mn84} cluster, shown, has a torus structure and is a single-molecule magnet (SMM). It represents a meeting of the molecular (bottom-up) and classical (top-down) approaches to nanoscale magnetic materials, and it crystallizes as nanotubular stacks.