Unravelling phenomenon of internal rotation in B13+ through chemical bonding analysis

著者: Gerardo Martínez‐Guajardo, Alina P. Sergeeva, Alexander I. Boldyrev, Thomas Heine, Jesús M. Ugalde, Gabriel Merino - Chemical Communications 2011 被引用: 154

We describe and explain the fluxionality of B(13)(+). The chemical bonding analysis shows that the inner triangle of B(13)(+) is bound to the peripheral ring by delocalized bonds only, allowing a quasi-free rotation of the inner ring.