Solid state organic amine detection in a photochromic porous metal organic framework

著者: Arijit Mallick, Bikash Garai, Matthew A. Addicoat, Petko St. Petkov, Thomas Heine, Rahul Banerjee - Chemical Science 2014 被引用: 373

A new Mg(ii) based porous metal–organic framework (MOF) has been synthesized from naphthalenediimide (NDI) chromophoric unit containing linker. This MOF (Mg–NDI) shows instant and reversible photochromism as well as solvatochromic behavior. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state.