Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

著者: Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig, Robert H. Crabtree - Journal of the American Chemical Society 2009 被引用: 591

A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.