Elucidating the activity, mechanism and application of selective electrosynthesis of ammonia from nitrate on cobalt phosphide

著者: Shenghua Ye, Zhida Chen, Guikai Zhang, Wenda Chen, Chao Peng, Xiuyuan Yang, Lirong Zheng, Yongliang Li, Xiangzhong Ren, Huiqun Cao, Dongfeng Xue, Jieshan Qiu, Qianling Zhang, Jianhong Liu - Energy & Environmental Science 2021 被引用: 375

Cobalt phosphide is an effective electrocatalyst for NO 3 − electroreduction into NH 3 . Phosphorus is crucial for stabilizing the active phase and optimizing energy barriers, and Co 4p orbitals directly participate in the nitrate reduction.