Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction

著者: Jingkun Li, Shraboni Ghoshal, Wentao Liang, Moulay Tahar Sougrati, Frédéric Jaouen, Barr Halevi, Samuel McKinney, Geoff McCool, Chunrong Ma, Xianxia Yuan, Zi‐Feng Ma, Sanjeev Mukerjee, Qingying Jia - Energy & Environmental Science 2016 被引用: 579

The biomimetic dynamic nature of the Fe–N–C active site with a near-optimal Fe2+/3+redox potential facilitates ORR by balancing the site-blocking effect and O2dissociation.